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A Study of Peroxyoxalate-Chemiluminescence of 4,4'-bis{[4,6-bis (2-hydroxyethyl)amino-1,3,5-triazin-2-yl]amino}stilbene-2,2'-disulfonic Acid-Disodium Salt as a Novel Blue Fluorescer

A Study of Peroxyoxalate-Chemiluminescence of 4,4'-bis{[4,6-bis (2-hydroxyethyl)amino-1,3,5-triazin-2-yl]amino}stilbene-2,2'-disulfonic Acid-Disodium Salt as a Novel Blue Fluorescer

Mojtaba Shamsipur, Ali Yeganeh-Faal, Mohammad Javad Chaichi, Mahmood Tajbakhsh, Ali Parach

Spectrochim Acta A Mol Biomol Spectrosc. 2007 Mar;66(3):546-51.

PMID: 16859973

Abstract:

The chemiluminescence arising from the reaction of bis(2,4,6-trichlorophenyl)oxalate (TCPO) with hydrogen peroxide in the presence of brightener 4,4'-bis{[4,6-bis(2-hydroxyethyl)amino-1,3,5-triazin-2-yl]amino}stilbene-2,2'-disulfonic acid-disodium salt (Triazinyl) has been studied. The influence of concentration of TCPO, hydrogen peroxide, Triazinyl, base catalysts and temperature on the resulting chemiluminescence was investigated. The kinetic parameters for the peroxyoxalate-chemiluminescence (PO-CL) of Triazinyl were evaluated from computer fitting of the resulting intensity-time plots. The activation energies, E(a), were evaluated from temperature dependence of the corresponding rise and fall rate constants.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP75203519	Bis(2-carbopentyloxy-3,5,6-trichlorophenyl) oxalate		75203-51-9	Price

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