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(Acetylacetonato-κ2O,O')[1-(4-bromophenyl-κC2)-3-methylimidazol-2-ylidene-κC2]platinum(II)

(Acetylacetonato-κ2O,O')[1-(4-bromophenyl-κC2)-3-methylimidazol-2-ylidene-κC2]platinum(II)

Mario Tenne, Yvonne Unger, Thomas Strassner

Acta Crystallogr C. 2012 Aug;68(Pt 8):m203-5.

PMID: 22850842

Abstract:

The title platinum(II) complex, [Pt(C(10)H(8)BrN(2))(C(5)H(7)O(2))], has a bidentate cyclometallated phenylimidazolylidene ligand and an acetylacetonate spectator ligand, which form a distorted square-planar coordination environment around the Pt(II) centre. In the solid state, the molecules are oriented in a parallel fashion by intermolecular hydrogen bonding and π-π and C-H···π interactions, while close Pt···Pt contacts are not observed. The structure is only the second example for this new class of compounds.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP15170577	Platinum(II) acetylacetonate		15170-57-7	Price

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