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Catecholborane

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For Research Use Only | Not For Clinical Use
CATAP274077-A
CAS274-07-7
Structure
MDL NumberMFCD00005846
Molecular Weight119.91
EC Number205-991-5
InChI KeyCENMEJUYOOMFFZ-UHFFFAOYSA-N
REAXYS Number972072
Description98%
Density1.125 g/mL at 25 °C (lit.)
Assay98%
BP50 °C/50 mmHg (lit.)
MP12 °C (lit.)
Refractive Indexn20/D 1.507 (lit.)
Size25G, 100G
Storage Conditions2-8°C
1

Asymmetric Reduction of Ketones With Catecholborane Using 2,6-BODOL Complexes of titanium(IV) as Catalysts

I Sarvary, F Almqvist, T Frejd

Chemistry. 2001 May 18;7(10):2158-66.

PMID: 11411988

1

B(C 6 F 5) 3-Catalyzed C3-Selective C-H Borylation of Indoles: Synthesis, Intermediates, and Reaction Mechanism

Sutao Zhang, Yuxi Han, Jianghua He, Yuetao Zhang

J Org Chem. 2018 Feb 2;83(3):1377-1386.

PMID: 29284261

1

Dihydridoboranes: Selective Reagents for Hydroboration and Hydrodefluorination

Nicholas A Phillips, James O'Hanlon, Thomas N Hooper, Andrew J P White, Mark R Crimmin

Org Lett. 2019 Sep 20;21(18):7289-7293.

PMID: 31497960

1

Photoswitching of the Lewis Acidity of a Catecholborane Bearing an Azo Group Based on the Change in Coordination Number of Boron

Naokazu Kano, Junro Yoshino, Takayuki Kawashima

Org Lett. 2005 Sep 1;7(18):3909-11.

PMID: 16119929

1

Tautomerization of 2,6-lutidines in the Presence of B(C6F5)3 Using Catecholborane as a Precatalyst

Junhao Zheng, Xiaoting Fan, Benyu Zhou, Zhen Hua Li, Huadong Wang

Chem Commun (Camb). 2016 Mar 28;52(25):4655-8.

PMID: 26947739

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