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Pentamethyldisilane

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For Research Use Only | Not For Clinical Use
CATAP812157
CAS812-15-7
Structure
MDL NumberMFCD03427188
Molecular Weight132.35
InChI KeyFHQRQPAFALORSL-UHFFFAOYSA-N
Description97%
Density0.722 g/mL at 25 °C (lit.)
Assay97%
BP98-99 °C (lit.)
Formliquid
Linear Formula(CH3)3SiSi(CH3)2H
Refractive Indexn20/D 1.4240 (lit.)
Size5ML
1

Determination of the Equilibrium Structure of the Charge-Transfer State of (p-Cyanophenyl)pentamethyldisilane by Means of Transient Infrared Spectroscopy

Haruki Ishikawa, Masuyuki Sugiyama, Ippei Baba, Wataru Setaka, Mitsuo Kira, Naohiko Mikami

J Phys Chem A. 2005 Oct 13;109(40):8959-61.

PMID: 16331997

1

Direct Observation of the Solvent Reorientation Dynamics in the "Twisted" Intramolecular Charge-Transfer Process of Cyanophenyldisilane-Water Cluster by Transient Infrared Spectroscopy

Haruki Ishikawa, Masuyuki Sugiyama, Wataru Setaka, Mitsuo Kira, Naohiko Mikami

Phys Chem Chem Phys. 2007 Jan 7;9(1):117-26.

PMID: 17164893

1

Intramolecular Charge-Transfer Process of Jet-Cooled (P-Cyanophenyl)pentamethyldisilane: Roles of the Torsional Motion and the Si-Si Bond Change

Haruki Ishikawa, Yoichi Shimanuki, Masuyuki Sugiyama, Yuko Tajima, Mitsuo Kira, Naohiko Mikami

J Am Chem Soc. 2002 May 29;124(21):6220-30.

PMID: 12022858

1

Platinum-catalyzed Addition of Dimethylsilylene to Beta-Methyl Alpha,beta-Unsaturated Ketones: Gamma-Silylation Forming 1-oxa-2-silacyclohex-5-enes

Kazuhiro Okamoto, Tamio Hayashi

Org Lett. 2007 Nov 22;9(24):5067-9.

PMID: 17973489

1

Solvent Reorientation Process in the "Twisted" Intramolecular Charge-Transfer Process of cyanophenyldisilane-(H2O)2 Cluster Investigated by Transient Infrared Spectroscopy

Masuyuki Sugiyama, Haruki Ishikawa, Wataru Setaka, Mitsuo Kira, Naohiko Mikami

J Phys Chem A. 2008 Feb 14;112(6):1168-71.

PMID: 18217736

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