CAS 81290-20-2 Trimethyl(trifluoromethyl)silane - Analytical Products / Alfa Chemistry

CAT	AP81290202
CAS	81290-20-2
Structure
MDL Number	MFCD00145454
Molecular Weight	142.19
InChI Key	MWKJTNBSKNUMFN-UHFFFAOYSA-N
REAXYS Number	4241868

Description	99%
Density	0.962 g/mL at 20 °C (lit.)
Assay	99%
BP	54-55 °C (lit.)
Linear Formula	(CH3)3SiCF3
Size	5ML, 25ML
Storage Conditions	2-8°C

1

Benzoyl Peroxide (BPO)-promoted Oxidative Trifluoromethylation of Tertiary Amines With Trimethyl(trifluoromethyl)silane

Lingling Chu, Feng-Ling Qing

Chem Commun (Camb). 2010 Sep 14;46(34):6285-7.

PMID: 20694243

1

Catalytic Enantioselective Trifluoromethylation of Azomethine Imines With Trimethyl(trifluoromethyl)silane

Hiroyuki Kawai, Akihiro Kusuda, Shuichi Nakamura, Motoo Shiro, Norio Shibata

Angew Chem Int Ed Engl. 2009;48(34):6324-7.

PMID: 19606438

1

How Trimethyl(trifluoromethyl)silane Reacts With Itself in the Presence of Naked Fluoride--A One-Pot Synthesis of bis([15]crown-5)cesium 1,1,1,3,5,5,5-heptafluoro-2,4-bis(trifluoromethyl)pentenide

Wieland Tyrra, Mikhail M Kremlev, Dieter Naumann, Harald Scherer, Harald Schmidt, Berthold Hoge, Ingo Pantenburg, Yurii L Yagupolskii

Chemistry. 2005 Nov 4;11(22):6514-8.

PMID: 16121407

1

Stereoselective Nucleophilic Trifluoromethylation of N-(tert-Butylsulfinyl)imines by Using Trimethyl(trifluoromethyl)silane

G K Surya Prakash, Mihirbaran Mandal, George A Olah

Angew Chem Int Ed Engl. 2001 Feb 2;40(3):589-590.

PMID: 29712018

1

Stereoselective Nucleophilic Trifluoromethylation of N-(tert-Butylsulfinyl)imines by Using Trimethyl(trifluoromethyl)silane Support of Our Work by Loker Hydrocarbon Research Institute Is Gratefully Acknowledged

G. K. Surya Prakash, Mihirbaran Mandal, George A. Olah

Angew Chem Int Ed Engl. 2001 Feb 2;40(3):589-590.

PMID: 11180380

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