(5R)-5-[(1R)-2,2-Dichloro-1-methyl-cyclo-prop-yl]-2-methyl-cyclo-hex-2-en-1-one

Brahim Boualy, Mohamed Anoir Harrad, Larbi El Firdoussi, Mustapha Ait Ali, Corrado Rizzoli

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):o1638.

PMID: 21837043

Abstract:

The title compound, C(11)H(14)Cl(2)O, was synthesized by the reaction of a dichloro-methane solution of (R)-carvone and potassium tert-butano-late in the presence of a catalytic amount of benzyl-triethyl-ammonium chloride in chloro-form. The cyclo-hexene ring adopts a half-boat conformation. The cyclo-propyl ring is unsymmetrical, the shortest C-C bond being distal to the alkyl-substituted C atom. The crystal packing is stabilized only by van der Waals inter-actions.

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