Home
Resources
Publications
[FTIR Spectral Analysis of Saturated Solution During Dissolution and Transformation of Chloropinnoite in Magnesium Chloride Solution]

[FTIR Spectral Analysis of Saturated Solution During Dissolution and Transformation of Chloropinnoite in Magnesium Chloride Solution]

Zhi-hong Liu, Shi-yang Gao, Shu-ping Xia

Guang Pu Xue Yu Guang Pu Fen Xi. 2003 Apr;23(2):291-3.

PMID: 12961874

Abstract:

FTIR differential spectroscopy was used to identify the polyborate ions in saturated aqueous solutions during dissolution and transformation of 2MgO.2B2O3.MgCl2.14H2O in 0.5%, 12%, and 18% MgCl2 solutions at 30 degrees C, respectively. The recorded IR-spectroscopic frequencies of the borate aqueous solution subtracted that of water as a blank value and their assignments were given. The bands at about 515, 630 and 550 cm-1 are characteristics of B(OH)4-/B2O(OH)6(2-), B3O3(OH)4-/B3O3(OH)5(2-), and B4O5(OH)4(2-), respectively. The existing forms of polyborate anions in saturated aqueous solutions and their interaction have been discussed. The relations between the existing forms of polyborate anions and the crystallizing solid phases have been obtained.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP7786303	Magnesium chloride solution		7786-30-3	Price

As a specialist in analytical chemical Products, Alfa Chemistry offers consumers a wealth of raw materials and a full range of technologies and services.

QUICK LINKS

HEADQUARTERS

Tel:

Fax:

Email: