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In Situ Generation of O-Iodoxybenzoic Acid (IBX) and the Catalytic Use of It in Oxidation Reactions in the Presence of Oxone as a Co-Oxidant

In Situ Generation of O-Iodoxybenzoic Acid (IBX) and the Catalytic Use of It in Oxidation Reactions in the Presence of Oxone as a Co-Oxidant

Arun P Thottumkara, Michael S Bowsher, Thottumkara K Vinod

Org Lett. 2005 Jul 7;7(14):2933-6.

PMID: 15987173

Abstract:

[structure: see text] Catalytic use of o-iodoxybenzoic acid (IBX) in the presence of Oxone as a co-oxidant is demonstrated for the oxidation of primary and secondary alcohols in user- and eco-friendly solvent mixtures. Also demonstrated is the in situ (re)oxidation of 2-iodosobenzoic acid (IBA) and even commercially available 2-iodobenzoic acid (2IBAcid) by Oxone to IBX allowing one to use these less hazardous reagents, in place of potentially explosive IBX, as catalytic oxidants.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP304916	2-Iodosobenzoic acid		304-91-6	Price

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