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[1,1'-Bis(dicyclo-hexyl-phosphino)cobalto-cenium-κP,P']chlorido(η-cyclo-penta-dien-yl)ruthenium(II) Hexa-Fluorido-Phosphate

Jian-Guo Hou

Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 30;66(Pt 2):m218.

PMID: 21579679

Abstract:

In the title structure, [CoRu(C(5)H(5))(C(17)H(26)P)(2)Cl]PF(6), the Ru(II) atom is bonded to a cyclo-penta-dienyl ring, a Cl atom and two P atoms of the chelating 1,1'-bis-(dicyclo-hexyl-phosphino)cobaltocenium (di-cypc) ligand, leading to a three-legged piano-stool coordination. Part of the PF(6) (-) counter-anion is disordered over two positions, with a site-occupancy ratio of 0.898 (7):0.102 (7). The components are linked by C-H⋯F and C-H⋯Cl hydrogen bonds.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP1287134 Bis(cyclopentadienyl)ruthenium(II) Bis(cyclopentadienyl)ruthenium(II) 1287-13-4 Price
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