Home
Resources
Publications
6-Coordinate tungsten(VI) Tris-N-Isopropylanilide Complexes: Products of Terminal Oxo and Nitrido Transformations Effected by Main Group Electrophiles

6-Coordinate tungsten(VI) Tris-N-Isopropylanilide Complexes: Products of Terminal Oxo and Nitrido Transformations Effected by Main Group Electrophiles

Christopher R Clough, Peter Müller, Christopher C Cummins

Dalton Trans. 2008 Sep 7;(33):4458-63.

PMID: 18698449

Abstract:

The nitridotungsten(vi) complex NW(N[i-Pr]Ar)(3) (-N, Ar = 3,5-Me(2)C(6)H(3)) reacts with (CF(3)C(O))(2)O followed by ClSiMe(3) to give the isolable trifluoroacetylimido-chloride complex -(NC(O)CF(3))Cl, with oxalyl chloride to give cyanate-dichloride -(OCN)(Cl)(2), and with PCl(5) to give trichlorophosphinimide-dichloride -(NPCl(3))(Cl)(2). The oxo-chloride complex -(O)Cl, obtained from -N upon treatment with pivaloyl chloride, reacts with PCl(5) to give trichloride -(Cl)(3). Synthetic and structural details are reported for the new tungsten trisanilide derivatives.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP13283017	Tungsten(VI) chloride		13283-01-7	Price

As a specialist in analytical chemical Products, Alfa Chemistry offers consumers a wealth of raw materials and a full range of technologies and services.

QUICK LINKS

HEADQUARTERS

Tel:

Fax:

Email: