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A Catalytically Active, Permanently Microporous MOF With Metalloporphyrin Struts

Abraham M Shultz, Omar K Farha, Joseph T Hupp, SonBinh T Nguyen

J Am Chem Soc. 2009 Apr 1;131(12):4204-5.

PMID: 19271705

Abstract:

Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl)benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
LS72549 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene Price
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