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A Facile Single Crystal to Single Crystal Transition With Significant Structural Contraction on Desolvation

Jane V Knichal, William J Gee, Andrew D Burrows, Paul R Raithby, Simon J Teat, Chick C Wilson

Chem Commun (Camb). 2014 Nov 28;50(92):14436-9.

PMID: 25303036

Abstract:

5-Ethynyl-1,3-benzenedicarboxylic acid (H2ebdc) reacted with lead(II) acetate trihydrate yields a 1D ladder network, [Pb(ebdc)(MeOH)]2·H2O (1). Removing crystals of 1 from the mother liquor results in a facile single crystal to single crystal transition, yielding 2D [Pb(ebdc)] net (2) with a change in space group from I2/a to P1̄.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP432025973 5-Ethynyl-1,3-benzenedicarboxylic acid 5-Ethynyl-1,3-benzenedicarboxylic acid 432025-97-3 Price
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