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A Library of Atmospheric Pressure Ionization Daughter Ion Mass Spectra Based on Wideband Excitation in an Ion Trap Mass Spectrometer

C Baumann, M A Cintora, M Eichler, E Lifante, M Cooke, A Przyborowska, J M Halket

Rapid Commun Mass Spectrom. 2000;14(5):349-56.

PMID: 10700037

Abstract:

A searchable library of MS/MS spectra obtained using a quadrupole ion trap mass spectrometer and electrospray or atmospheric pressure chemical ionization is presented. The application of wideband excitation (activation) and normalized collision energy leads to highly reproducible mass spectra which are searched using the NIST algorithm. Flow injection and LC/MS/MS applications of this powerful technique in the biomedical (diastereoisomeric steroids, morphine glucuronides, isovalerylcarnitine) and environmental (pirimicarb and desmethyl-pirimicarb) areas are described.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP30614223 Desmethyl-pirimicarb Desmethyl-pirimicarb 30614-22-3 Price
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