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A Multilayer Assembly of Two Mixed-Valence Mn16-containing Polyanions and Study of Their Electrocatalytic Activities Towards Water Oxidation

A Multilayer Assembly of Two Mixed-Valence Mn16-containing Polyanions and Study of Their Electrocatalytic Activities Towards Water Oxidation

Yu Du, Tian Yu, Zhijing Fu, Lihua Bi

Dalton Trans. 2018 May 29;47(21):7282-7289.

PMID: 29767656

Abstract:

Herein, two mixed-valence Mn16-containing polyanions, (Mn16) [MnIII10MnII6O6(OH)6(PO4)4(A-a-SiW9O34)4]28- (Mn16-Cs) and [MnIII4MnII12(OH)12(PO4)4(A-a-SiW9O34)4]28- (Mn16-Rb), were successfully fabricated on an indium tin oxide (ITO)-coated glass electrode and a glass carbon electrode (GCE) by a layer-by-layer assembly method. Moreover, four composite films, i.e. [PDDA/Mn16-Cs]n, [PDDA/Mn16-Rb]n, [Mn16-Cs/Rubpy]n, and [Mn16-Rb/Rubpy]n (PDDA: poly(diallyldimethylammonium chloride); Rubpy: tris(2,2'-bipyridyl)ruthenium(ii) chloride; n = 1-10), were constructed for comparison and characterized by UV-visible spectroscopy, cyclic voltammetry (CV), and X-ray photoelectron spectroscopy (XPS). Their electrocatalytic activities towards water oxidation were studied under the same experimental conditions. The results of the controlled experiments indicate that (1) all the four films exhibit expected electrocatalytic activities towards water oxidation; (2) the electrocatalytic activity of Mn16-Cs is better than that of Mn16-Rb in solution and composite films; and (3) the electrocatalytic activities of the composite film [Mn16/Rubpy]n are better than those of the composite film [PDDA/Mn16]n.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP13465117	Indium(II) chloride		13465-11-7	Price

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