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A New Two-Dimensional Polymeric cadmium(II) Complex Containing Dicyanamide Bridging Ligands

A New Two-Dimensional Polymeric cadmium(II) Complex Containing Dicyanamide Bridging Ligands

Yang Lu, Wei Qiang Liao, Xiu Ni Hua

Acta Crystallogr C Struct Chem. 2017 Nov 1;73(Pt 11):885-888.

PMID: 29111514

Abstract:

As part of an exploration of new coordination polymers, a cadmium-dicyanamide complex, namely poly[benzyltriethylammonium [tri-μ-dicyanamido-κ6N1:N5-cadmium(II)]], {(C13H22N)[Cd(C2N3)3]}n, has been synthesized by the reaction of benzyltriethylammonium bromide, cadmium nitrate tetrahydrate and sodium dicyanamide in aqueous solution, and characterized by single-crystal X-ray diffraction at room temperature. In the crystal structure, each CdII cation is coordinated by six nitrile N atoms from six anionic dicyanamide (dca) ligands to furnish a slightly distorted octahedral geometry. Neighbouring CdII cations are linked by dicyanamide bridges to construct a two-dimensional anionic layer coordination polymer. One amide N atom in the bridging dca ligand is disordered over two sites. The cations lie between the anionic frameworks and there are no hydrogen-bond interactions between the cations and anions. The organic cations are not involved in the formation of the supramolecular network.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP10022681	Cadmium nitrate tetrahydrate		10022-68-1	Price

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