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A Novel Cetyltrimethyl Ammonium Silver Bromide Complex and Silver Bromide Nanoparticles Obtained by the Surfactant Counterion

Xian-Hao Liu, Xiao-Hong Luo, Shu-Xia Lu, Jing-Chang Zhang, Wei-Liang Cao

J Colloid Interface Sci. 2007 Mar 1;307(1):94-100.

PMID: 17188288

Abstract:

A novel cetyltrimethyl ammonium silver bromide (CTASB) complex has been prepared simply through the reaction of silver nitrate with cetyltrimethyl ammonium bromide (CTAB) in aqueous solution at room temperature by controlling the concentration of CTAB and the molar ratio of CTAB to silver nitrate in the reaction solution, in which halogen in CTAB is used as surfactant counterion. The structure and thermal behavior of cetyltrimethyl ammonium silver bromide have been investigated by using X-ray diffraction (XRD), infrared spectroscopy (IR), X-ray photoelectron spectroscopy (XPS), UV/vis spectroscopy, thermal analysis (TG-DTA), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The results show that the complex possesses a metastable layered structure. Upon heating the CTASB aqueous dispersion to above 80 degrees C, the structure change of the complex took place and CTAB-capped nanosized silver bromide particles further formed.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP12265064 Ammonium-d4 bromide Ammonium-d4 bromide 12265-06-4 Price
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