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A Novel Electrophilic Diamination Reaction of Alkenes

Guigen Li, Han-Xun Wei, Sun Hee Kim, Michael D Carducci

Angew Chem Int Ed Engl. 2001 Nov 19;40(22):4277-4280.

PMID: 29712117

Abstract:

A three-component electrophilic reaction transforms olefins into imidazoline and diamine derivatives. Rhodium(II) heptafluorobutyrate dimer (2 mol %) was utilized as the catalyst and N,N-dichloro-p-toluenesulfonamide (TsNCl2 ) and acetonitrile as the nitrogen sources. Modest to good yields (45-82 %) and high regio- and stereoselectivity were achieved.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP73755289 Rhodium(II) heptafluorobutyrate dimer Rhodium(II) heptafluorobutyrate dimer 73755-28-9 Price
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