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A Pd(II)-catalyzed Asymmetric Approach Toward Chiral [3.3.1]-bicyclic Ketals Using 2-hydroxyphenylboronic Acid as a Pro-Bis(nucleophile)

A Pd(II)-catalyzed Asymmetric Approach Toward Chiral [3.3.1]-bicyclic Ketals Using 2-hydroxyphenylboronic Acid as a Pro-Bis(nucleophile)

Feijun Wang, Feng Chen, Mingliang Qu, Teng Li, Yunlong Liu, Min Shi

Chem Commun (Camb). 2013 Apr 25;49(32):3360-2.

PMID: 23505627

Abstract:

Enantioselective Pd(II)-catalyzed construction of [3.3.1]-bicyclic ketals from 2-hydroxyphenylboronic acid and enone is reported, yielding enantioenriched [3.3.1]-bicyclic ketals in up to 97% yields and 98% ee.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
LS793859	2-Hydroxyphenylboronic acid			Price

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