0

A Ruthenium-Catalyzed Coupling of Alkynes With 1,3-Diketones

Megan K Pennington-Boggio, Brian L Conley, Travis J Williams

J Organomet Chem. 2012 Oct 1;716:6-10.

PMID: 22923850

Abstract:

Ruthenium(III) chloride hydrate is a convenient catalyst for the addition of active methylene compounds to aryl alkynes. These reactions are rapid, operationally simple, and high yielding in cases. Most significantly, no precautions are required to exclude air or water from the reactions. All reagents are commercially available at reasonable prices, and the reactions can be conducted in disposable glassware with minimal solvent.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP14898670 Ruthenium(III) chloride hydrate Ruthenium(III) chloride hydrate 14898-67-0 Price
qrcode