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A ruthenium porphyrin-based porous organic polymer for the hydrosilylative reduction of CO 2 to formate

Grace M Eder, David A Pyles, Eric R Wolfson, Psaras L McGrier

Chem Commun (Camb). 2019 Jun 25;55(50):7195-7198.

PMID: 31165111

Abstract:

A ruthenium porphyrin-based porous organic polymer (POP) was synthesized, characterized, and used to reduce CO2 to a formate salt. We demonstrate that Ru-BBT-POP can be utilized to reduce CO2 to a silyl formate and then converted to potassium formate with a respectable turnover number and frequency.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP590294 Potassium formate Potassium formate 590-29-4 Price
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