Home
Resources
Publications
A Samarium-Doped Carbon Aerogel Cathode With Anchored Polysulfides for Lithium-Sulfur Batteries With High Electrochemical Performance: A Metal-Organic Framework Template Method

A Samarium-Doped Carbon Aerogel Cathode With Anchored Polysulfides for Lithium-Sulfur Batteries With High Electrochemical Performance: A Metal-Organic Framework Template Method

Huijuan Sheng, Xueliang Li, Birou Huang, Jihong Wang, Xiaoyang Li, Yang Hua

Chempluschem. 2019 Jul;84(7):838-844.

PMID: 31943985

Abstract:

A samarium-doped carbon aerogel cathode (CA-Sm) for high-performance lithium-sulfur batteries was successfully synthesized from a Sm-containing metal-organic framework (MOF) as a template through a sol-gel reaction and a carbonization process. Sm-MOF doping plays an important role in regulating the structure of the gel and promoting the formation of samarium oxide in an amorphous state that is uniformly dispersed among the carbon spheres. A CA/S/Sm electrode delivers an initial discharge capacity of 1322 mAh g-1 at a rate of 0.2 C. Furthermore, it possesses an initial discharge capacity of 1212 mAh g-1 at 0.5 C and still maintains a value of 866 mAh g-1 after 300 cycles. Both the anchoring of polysulfides to uniformly doped Sm and the influence of the Sm-MOF on the CA structure lead to the excellent performance of the battery, and effectively prevent polysulfides escaping from cathode, while suppressing the shuttle effect and enhancing the utilization of sulfur.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP12060581-A	Samarium(III) oxide dispersion		12060-58-1	Price

As a specialist in analytical chemical Products, Alfa Chemistry offers consumers a wealth of raw materials and a full range of technologies and services.

QUICK LINKS

HEADQUARTERS

Tel:

Fax:

Email: