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Acetate/di-2-pyridyl Ketone Oximate "Blend" as a Source of High-Nuclearity nickel(II) Clusters: Dependence of the Nuclearity on the Nature of the Inorganic Anion Present

Acetate/di-2-pyridyl Ketone Oximate "Blend" as a Source of High-Nuclearity nickel(II) Clusters: Dependence of the Nuclearity on the Nature of the Inorganic Anion Present

Theocharis C Stamatatos, Eleanna Diamantopoulou, Catherine P Raptopoulou, Vassilis Psycharis, Albert Escuer, Spyros P Perlepes

Inorg Chem. 2007 Apr 2;46(7):2350-2.

PMID: 17328543

Abstract:

The use of di-2-pyridyl ketone oxime [(py)2CNOH] in reactions with Ni(O2CMe)2.4H2O, in the presence or absence of extra inorganic anions (N3- and SCN-) has led to Ni4, Ni5, and Ni7 clusters; the magnetic study of the heptanuclear nickel(II) complex reveals an S = 3 ground state.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP1562954	Di-2-pyridyl ketone oxime		1562-95-4	Price

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