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(Acetato-κO,O')bis-(1,10-phenanthroline-κN,N')copper(II) Trifluoro-Acetate Tetra-Hydrate

(Acetato-κO,O')bis-(1,10-phenanthroline-κN,N')copper(II) Trifluoro-Acetate Tetra-Hydrate

Jinxia Wang, Zhuping Jin

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 30;66(Pt 7):m865.

PMID: 21587769

Abstract:

In the title compound, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CF(3)CO(2))·4H(2)O, the Cu(II) atom shows a distorted octa-hedral coordination with four N atoms [Cu-N = 2.015 (3)-2.244 (3) Å] from the two phenanthroline ligands and two O atoms from the acetate [Cu-O = 1.953 (3) and 2.764 (3) Å]. Strong inter-molecular O-H⋯O hydrogen-bonding inter-actions consolidate the crystal packing. The F atoms of the anion are disordered over two positions in a 0.5233 (3):0.4767 (3) ratio.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP123333880	Copper(II) trifluoroacetate hydrate		123333-88-0	Price

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