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AgONO-assisted Direct C-H Arylation of Heteroarenes With Anilines

Saravanan Gowrisankar, Jayasree Seayad

Chemistry. 2014 Sep 26;20(40):12754-8.

PMID: 25137410

Abstract:

A novel copper-catalyzed C-H arylation of heteroarenes with anilines by an in situ diazonium reaction is established by using silver nitrite (AgONO) as an unconventional nitrosating reagent under acid-free conditions. It provides a complementary approach for the C-H arylation of electron-rich heteroarenes with aromatic amines affording a variety of heterobiaryls in moderate to good yields.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP7783995 Silver nitrite Silver nitrite 7783-99-5 Price
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