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Alternative Pathways to α,β-unsaturated Ketones via Direct Oxidative Coupling Transformation Using Sr-doped LaCoO

Alternative Pathways to α,β-unsaturated Ketones via Direct Oxidative Coupling Transformation Using Sr-doped LaCoO

Khang H Trinh, Son H Doan, Tien V Huynh, Phuong H Tran, Diep N Pham, Minh-Vien Le, Tung T Nguyen, Nam T S Phan

R Soc Open Sci. 2019 Nov 27;6(11):191313.

PMID: 31827863

Abstract:

A strontium-doped lanthanum cobaltite perovskite material was prepared, and used as a recyclable and effective heterogeneous catalyst for the direct oxidative coupling of alkenes with aromatic aldehydes to produce α,β-unsaturated ketones. The reaction afforded high yields in the presence of di-tert-butylperoxide as oxidant. Single oxides or salts of strontium, lanthanum and cobalt, and the undoped perovskite offered a lower catalytic activity than the strontium-doped perovskite. Benzaldehyde could be replaced by benzyl alcohol, dibenzyl ether, 2-oxo-2-phenylacetaldehyde, 2-bromoacetophenone or (dimethoxymethyl) benzene in the oxidative coupling reaction with alkenes. To our best knowledge, reactions between these starting materials with alkenes are new and unknown in the literature.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP108916092	Lanthanum strontium cobaltite, LSC-82		108916-09-2	Price

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