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An All-Solid-State Rechargeable Chloride Ion Battery

An All-Solid-State Rechargeable Chloride Ion Battery

Chao Chen, Tingting Yu, Meng Yang, Xiangyu Zhao, Xiaodong Shen

Adv Sci (Weinh). 2019 Jan 28;6(6):1802130.

PMID: 30937275

Abstract:

The chloride ion battery has been developed as one of the alternative battery chemistries beyond lithium ion, toward abundant material resources and high energy density. Its application, however, is limited by the dissolution of electrode materials and side reactions in the liquid electrolyte. Herein, a solid polymer electrolyte allowing chloride ion transfer and consisting of poly(ethylene oxide) as the polymer matrix, tributylmethylammonium chloride as the chloride salt, and succinonitrile as the solid plasticizer is reported. The as-prepared polymer electrolyte shows conductivities of 10-5-10-4 S cm-1 in the temperature range of 298-343 K. When it is assembled with the iron oxychloride/lithium electrode system, reversible electrochemical redox reactions of FeOCl/FeO at the cathode side and Li/LiCl at the anode side are realized, demonstrating the first all-solid-state rechargeable chloride ion battery.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP56375792	Tributylmethylammonium chloride		56375-79-2	Price

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