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Application of a Macroporous Resin Containing Imidazoline Groups to Preconcentration and Separation of Gold, Platinum and Palladium Prior to ICP-AES Determination

Application of a Macroporous Resin Containing Imidazoline Groups to Preconcentration and Separation of Gold, Platinum and Palladium Prior to ICP-AES Determination

Z X Su, Q S Pu, X Y Luo, X J Chang, G Y Zhan, F Z Ren

Talanta. 1995 Aug;42(8):1127-33.

PMID: 18966338

Abstract:

A new functional resin with a long functional side chain was synthesized by modification of aminated macroporous poly(vinyl chloride) resin with cyanoethylene and ethylenediamine. Traces of Au(III), Pt(IV) and Pd(II) in aqueous solution were quantitatively adsorbed in the acidity range of pH 4 and C(H(+)) 3 M. The rate of equilibration is high; Cu(2+), Fe(3+), Ni(2+), etc. exhibit little interference on the adsorption of the sought noble metals. The saturated adsorption capacities for Au(III), Pt(IV), Pd(II) and Ir(IV) in 2 M HCl were 4.0, 1.57, 2.26, 1.85 mmol g(-1). Adsorbed ions can be quantitatively desorbed by 4% thiourea +0.25 M H(2)SO(4). The resin has good reusability, and can be used for preconcentration and separation of Au(III), Pt(IV) and Pd(II) prior to their determination by ICP-AES with satisfactory results.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP15020992	(Ethylenediamine)palladium(II) chloride		15020-99-2	Price

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