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Aqua-trimeth-yl[2-(4-methyl-pyrimidin-2-ylsulfan-yl)acetato-κO]tin(IV)

Zhiqing Gao, Junhong Zhang, Xuyi Hao, Daqi Wang, Tingting Zhang

Acta Crystallogr Sect E Struct Rep Online. 2013 May 15;69(Pt 6):m313.

PMID: 23794980

Abstract:

In the title compound, [Sn(CH3)3(C7H7N2O2S)(H2O)], the Sn(IV) atom has a distorted trigonal-bipyramidal coordination geometry, with one carboxyl-ate O atom of the 2-(4-methyl-pyrimidine-2-sulfan-yl)acetate ligand and the O atom of a water mol-ecule in axial positions, and three methyl groups in equatorial positions. In the crystal, mol-ecules are linked via O-H⋯O and O-H⋯N hydrogen bonds, forming double-stranded chains propagating along [010].

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP2800966 Tin(IV) acetate Tin(IV) acetate 2800-96-6 Price
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