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Benz-amidinato Calcium Iodide Catalyzed Aldehyde and Ketone Hydroboration With Unprecedented Functional Group Tolerance

Sandeep Yadav, Sanjukta Pahar, Sakya S Sen

Chem Commun (Camb). 2017 Apr 20;53(33):4562-4564.

PMID: 28393955

Abstract:

A benz-amidinato calcium compound, [PhC(NiPr)2CaI] (1), catalyzed hydroboration of a wide range of aldehydes and ketones using pinacolborane (HBpin) at room temperature is reported. The catalyst shows functional group tolerance even towards OH and NH groups. The strategy was further extended to imines.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP10102688 Calcium iodide Calcium iodide 10102-68-8 Price
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