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Bis{μ-4,4',6,6'-tetra-tert-butyl-2,2'-[N-(2-oxidoeth-yl)imino-dimethyl-ene]diphenolato}dialuminium(III)

Stephanie L Hemmingson, Alice J Stevens, Joseph M Tanski, Yutan D Y L Getzler

Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 17;66(Pt 8):m937.

PMID: 21588169

Abstract:

The title compound, [Al(2)(C(32)H(48)NO(3))(2)], exists as a dimer with bridging ethoxide groups. It was isolated from a reaction mixture of the parent ligand and trimethyl-aluminium in tetra-hydro-furan. The geometry around the Al(III) atom is a slightly distorted trigonal-bipyramid, typical of atrane derivatives.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP555759 Aluminum ethoxide Aluminum ethoxide 555-75-9 Price
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