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Bis(chloro-acetato-κO,O')bis-(2-fluoro-benzyl-κC)tin(IV)

Bis(chloro-acetato-κO,O')bis-(2-fluoro-benzyl-κC)tin(IV)

Aixia Deng, Mouyong Teng, Qian Xie, Nana Yan

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1905.

PMID: 22199661

Abstract:

In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(7)H(6)F)(2)], the Sn(IV) atom is located on a twofold rotation axis and forms a strongly distorted trans-octa-hedral geometry. The equatorial plane is defined by two chelating chloro-acetate ligands with asymmetrical Sn-O bond lengths, while the axial positions are occupied by the C atoms of two 2-fluoro-benzyl groups. In the crystal, infinite chains in the [010] direction are formed through inter-molecular Sn⋯O inter-actions [Sn⋯O separation = 3.682 (3) Å].

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP2800966	Tin(IV) acetate		2800-96-6	Price

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