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Bridged silver(I) Complexes of the Polycyclic Aromatic Compounds Tetraphenylethylene and 1,1,4,4-tetraphenyl-1,3-butadiene

Bridged silver(I) Complexes of the Polycyclic Aromatic Compounds Tetraphenylethylene and 1,1,4,4-tetraphenyl-1,3-butadiene

I Ino, L P Wu, M Munakata, T Kuroda-Sowa, M Maekawa, Y Suenaga, R Sakai

Inorg Chem. 2000 Nov 27;39(24):5430-6.

PMID: 11154557

Abstract:

For the purpose of investigating the coordination behavior of the sterically congested alkenes and exploring the possibility of cofacial complexation in the polycyclic aromatic system for formation of extended polymeric networks, tetraphenylethylene (tphe) and 1,1,4,4-tetraphenyl-1,3-butadiene (tphb) have been studied with regard to their complexation with a silver(I) ion. The crystal structures of [Ag(tphe)(ClO4)(p-xylene)], [Ag2(tphe)(ClO4)2], [Ag4(tphe)(CF3SO3)4], [Ag2(tphb)(ClO4)2], and [Ag2(tphb)(CF3SO3)2], together with the metal-free ligands tphe and tphb, have been determined by single-crystal X-ray diffraction. The pi-electron-rich cleft in organic components is found to offer a potential site for complexation, which can be utilized to generate an interesting array of organometallic compounds with one- and two-dimensional frameworks.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP1450631	1,1,4,4-Tetraphenyl-1,3-butadiene		1450-63-1	Price

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