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Broadband Polarized Emission From P(NDI2OD-T2) Polymer

Broadband Polarized Emission From P(NDI2OD-T2) Polymer

Steven V Ulrich, Tabitha Sutch, Greg Szulczewski, Matthias Schweizer, Newton M Barbosa Neto, Paulo T Araujo

J Phys Condens Matter. 2018 Jul 4;30(26):265101.

PMID: 29775180

Abstract:

We investigate the P(NDI2OD-T2) photophysical properties via absorbance and fluorescence spectroscopy, in association with the experimental approach baptized Stokes Spectroscopy, which provides valuable material information through the acquisition and analysis of the fluorescence polarization degree. By changing solvents and using different samples such as solutions, thick, and thin films, it is possible to control the polarization degree spectrum associated to the fluorescence emitted by the polymer's isolated chains and aggregates. We show that the polarization degree could become a powerful tool to obtain information related to the samples morphology, which is connected to their microscopic structure. Moreover, the polarization degree spectra suggest that depolarization effects linked to energy and charge transfer mechanisms are likely taking place. Our findings indicate that P(NDI2OD-T2) polymers are excellent candidates for the advancement of organic technologies that rely on the emission and detection of polarized lights.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP1100243400	P(NDI2OD-T2)		1100243-40-0	Price

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