0

C-C Bond Formation With Carbon Dioxide Promoted by a Silver Catalyst

Satoshi Kikuchi, Kohei Sekine, Tomonobu Ishida, Tohru Yamada

Angew Chem Int Ed Engl. 2012 Jul 9;51(28):6989-92.

PMID: 22674562

Abstract:

A catalytic amount of silver benzoate with 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD) was an effective catalytic system for the reaction of carbon dioxide with various ketones containing an alkyne group at an appropriate position. These reactions afforded the corresponding γ-lactone derivatives in good to high yields under mild conditions.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP532310 Silver benzoate Silver benzoate 532-31-0 Price
qrcode