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Carbon Disulfide-Modified Magnetic Ion-Imprinted chitosan-Fe(III): A Novel Adsorbent for Simultaneous Removal of Tetracycline and Cadmium

Carbon Disulfide-Modified Magnetic Ion-Imprinted chitosan-Fe(III): A Novel Adsorbent for Simultaneous Removal of Tetracycline and Cadmium

Anwei Chen, Cui Shang, Jihai Shao, Yiqing Lin, Si Luo, Jiachao Zhang, Hongli Huang, Ming Lei, Qingru Zeng

Carbohydr Polym. 2017 Jan 2;155:19-27.

PMID: 27702503

Abstract:

A novel composite of carbon disulfide-modified magnetic ion-imprinted chitosan-Fe(III), i.e., MMIC-Fe(III) composite, was prepared as an efficient adsorbent for the simultaneous removal of tetracycline (TC) and Cd(II). This adsorbent showed excellent performance in removing TC and Cd(II) due to its rapid kinetics, high adsorption capacity, good reusability, and was well suited for use with real water samples. Kinetics studies demonstrated that the adsorption proceeded according to a pseudo-second order model. The adsorption isotherms were well described by the Langmuir model, with maximum adsorption capacity for TC and Cd(II) being 516.29 and 194.31mg/g, respectively. The synergistic effect of TC and Cd(II) adsorption might be due to the formation of TC-Cd(II) complex bridging the adsorbate and adsorbent. These properties demonstrate the potential application of MMIC-Fe(III) for the simultaneous removal of TC and Cd(II), and may provide some information for the synergistic removal of antibiotics and heavy metals from aquatic environments.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP10022681	Cadmium nitrate tetrahydrate		10022-68-1	Price

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