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Catalytic Deoxydehydration of Glycols With Alcohol Reductants

Camille Boucher-Jacobs, Kenneth M Nicholas

ChemSusChem. 2013 Apr;6(4):597-9.

PMID: 23532937

Abstract:

Top shelf dehydration: Ammonium perrhenate catalysts combined with benzylic alcohol reductants are used for the efficient deoxydehydration of glycols to olefins. The olefin and aldehyde products can be easily separated and isolated. It is also demonstrated that the catalyst can be recovered and reused because of its low solubility in aromatic solvents.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP13598657 Ammonium perrhenate Ammonium perrhenate 13598-65-7 Price
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