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catena-poly[[(acetonitrile-N)dichlorocopper(II)]-mu-2,5-dimethylpyrazine-kappa2N:N']

catena-poly[[(acetonitrile-N)dichlorocopper(II)]-mu-2,5-dimethylpyrazine-kappa2N:N']

C Näther, J Greve

Acta Crystallogr C. 2001 Dec;57(Pt 12):1388-90.

PMID: 11740091

Abstract:

In the structure of the title compound, [CuCl2(C2H3N)(C6H8N2)], each Cu2+ cation is surrounded by two 2,5-dimethylpyrazine ligands, one acetonitrile ligand and two Cl- anions within a distorted tetragonal pyramid. The acetonitrile ligand, which forms the apex of the pyramid, the Cu2+ cation and the Cl- anions are all located in general positions, whereas each of the 2,5-dimethylpyrazine ligands is located about a centre of inversion. The 2,5-dimethylpyrazine ligands connect the Cu2+ cations via mu-N:N' coordination to form chains.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP123320	2,5-Dimethylpyrazine		123-32-0	Price

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