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catena-Poly[[[aqua-manganese(II)]-di-μ-sulfato-[aqua-manganese(II)]-μ-N,N,N',N'-tetra-kis(2-pyridylmeth-yl)hexane-1,6-diamine] Hexa-Hydrate]

catena-Poly[[[aqua-manganese(II)]-di-μ-sulfato-[aqua-manganese(II)]-μ-N,N,N',N'-tetra-kis(2-pyridylmeth-yl)hexane-1,6-diamine] Hexa-Hydrate]

Ah-Ran Song, In-Chul Hwang, Kwang Ha

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):m44.

PMID: 21200615

Abstract:

In the polymeric title compound, {[Mn(2)(SO(4))(2)(C(30)H(36)N(6))(H(2)O)(2)]·6H(2)O}(n), the two Mn(2+) ions are bridged by two sulfate anions to form dinuclear complexes, and these dinuclear species are linked by the hexa-dentate ligand N,N,N',N'-tetra-kis(2-pyridylmeth-yl)hexane-1,6-diamine (tphn), forming a one-dimensional chain structure running in the [101] direction. The repeat unit of the polymer, Mn(2)(SO(4))(2)(H(2)O)(2)(tphn), is disposed about a twofold axis passing through the centre of the dinuclear unit. The coordination geometry around the Mn centre is distorted octa-hedral. Two methylene groups are each disordered equally over two positions.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP111961876	N,N,N′,N′-Tetraphenylnaphthalene-2,6-diamine		111961-87-6	Price
AP15244367	Manganese(II) sulfate hydrate		15244-36-7	Price

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