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catena-Poly[bis-(μ(4)-adipato-1:2:1':2'κO:O:O:O)bis-(N,N-dimethyl-formamide)-1κO,2κO-dicopper(II)]

catena-Poly[bis-(μ(4)-adipato-1:2:1':2'κO:O:O:O)bis-(N,N-dimethyl-formamide)-1κO,2κO-dicopper(II)]

Guo-Yun Wu, Seik Weng Ng

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 15;66(Pt 10):m1258.

PMID: 21587406

Abstract:

In the title polymeric complex, [Cu(2)(C(6)H(8)O(4))(2)(C(3)H(7)NO)(2)](n), the carboxyl-ate groups of the approximately U-shaped adipate dianion each bridge a pair of inversion-related, DMF-coordinated copper(II) atoms, generating a ribbon motif that runs along the b axis. The geometry of the copper(II) atom is distorted square-pyramidal; the apical site is occupied by the O atom of the DMF mol-ecule whereas the four basal sites are occupied by carboxyl-ate O atoms.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP77916779	Bis(1-butylpentyl) adipate		77916-77-9	Price

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