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catena-Poly[bis-[octa-kis(dimethyl sulf-oxide)praseodymium(III)] hexa-μ(3)-sulfido-dodeca-μ(2)-sulfido-hexa-sul-fido-hexa-silverhexa-molybdenum]

catena-Poly[bis-[octa-kis(dimethyl sulf-oxide)praseodymium(III)] hexa-μ(3)-sulfido-dodeca-μ(2)-sulfido-hexa-sul-fido-hexa-silverhexa-molybdenum]

Zhengjing Jiang, Guodong Tang, Rongqing Li, Yu Zhang

Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 31;64(Pt 8):m1100-1.

PMID: 21203073

Abstract:

The title compound, {[Pr(C(2)H(6)OS)(8)](2)[Mo(6)Ag(6)S(24)]}(n), contains polymeric Mo(6)S(24)Ag(6) (2-) anions and [Pr(Me(2)SO)(8)](3+) cations, forming a one-dimensional polymeric Mo/S/Ag cluster. The anion assumes the conformation of a zigzag chain. The trivalent cations are arrayed amongst the anionic chains and are well separated from each other. Each Mo and Ag atom is coordinated by four S atoms in a distorted tetra-hedral geometry. The Pr(3+) atom is coordinated by eight dimethyl sulfoxide ligands, forming a polyhedron-shaped distorted square anti-prism.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP12036327	Praseodymium(III) oxide		12036-32-7	Price

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