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catena-Poly[[cobalt(II)-μ-aqua-μ-propano-ato-κO:O'-μ-propano-ato-κO:O] Monohydrate]

catena-Poly[[cobalt(II)-μ-aqua-μ-propano-ato-κO:O'-μ-propano-ato-κO:O] Monohydrate]

A I Fischer, V V Gurzhiy, A N Belyaev

Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 31;66(Pt 11):m1498.

PMID: 21588911

Abstract:

The title compound, {[Co(C(2)H(5)COO)(2)(H(2)O)]·H(2)O}(n), was synthesized by the reaction of cobalt(II) carbonate hydrate with aqueous propionic acid. The structure consists of polymeric infinite linear chains with composition [Co(C(2)H(5)COO)(4/2)(H(2)O)(2/2)](∞) running along [010]. The chains are formed by Co(2+) ions linked with bridging propionate groups and water mol-ecules, with a Co⋯Co distance along the chains of 3.2587 (9) Å. The Co(2+) ion is six-coordinated in a strongly distorted octa-hedral geometry. The chains are connected to each other by a network of O-H⋯O hydrogen bonds involving solvent water mol-ecules.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP57454678	Cobalt(II) carbonate hydrate		57454-67-8	Price

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