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Chlorido{N,N-dibenzyl-N,N-bis-[(diphenyl-phosphan-yl)meth-yl]pyridine-2,6-diamine}-methyl-platinum(II)

Zi-Jia Wang, Xiao-Xi Wang, Chong-Qing Wan

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):m1341-2.

PMID: 21587470

Abstract:

In the title mononuclear complex, [Pt(CH(3))Cl(C(45)H(41)N(3)P(2))], the pyridine-2,6-diamine ligand can be viewed as a centrosymmetric motif having two pendant N-benzyl-N-[(diphenyl-phosphan-yl)meth-yl] arms, the two P atoms of which chelate to the Pt(II) ion, forming a ten-membered metallocycle. A distorted square-planar coordination geometry around the Pt(II) atom is completed by a methyl ligand and a chloride ion. The packing between the mononuclear units is achieved through C-H⋯π inter-actions, which link the mol-ecules into chains along the c axis.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP111961876 N,N,N′,N′-Tetraphenylnaphthalene-2,6-diamine N,N,N′,N′-Tetraphenylnaphthalene-2,6-diamine 111961-87-6 Price
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