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cis-Bis[1-allyl-3-(2-pyrid-yl-κN)thio-ureato-κS]palladium(II)

cis-Bis[1-allyl-3-(2-pyrid-yl-κN)thio-ureato-κS]palladium(II)

Svitlana Orysyk, Volodimir Bon, Vasily Pekhnyo

Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 12;65(Pt 9):m1059.

PMID: 21577418

Abstract:

Yellow plate-like shaped crystals of the title compound, [Pd(C(9)H(10)N(3)S)(2)], were obtained by ligand-exchange reaction between palladium(II) acetyl-acetonate and the corresponding organic reagent at room temperature. The Pd(II) atom shows a slightly distorted square-planar coordination geometry consisting of two ligand mol-ecules in a cis conformation that bind in their thio-lic tautomeric form. Weak inter-molecular Pd⋯H inter-actions with Pd-H distances of 3.328 (2) Å were observed in the crystal structure. The three-dimensional network of the crystal structure is realized by weak inter-molecular C-H⋯N, N-H⋯N and C-H⋯S hydrogen bonds.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP14024614	Palladium(II) acetylacetonate		14024-61-4	Price

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