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Complexation of Asymmetric Diborenes With Magnesium Bromide

Wei Lu, Rei Kinjo

Chem Commun (Camb). 2018 Aug 7;54(64):8842-8844.

PMID: 30027954

Abstract:

The synthesis of neutral Mg complexes of asymmetric diborenes is reported. X-ray diffraction analysis reveals that the Mg center is unsymmetrically coordinated to the B2 units of diborenes. Theoretical calculations manifest the donation of electrons from the π-type orbitals of diborenes to an empty orbital of Mg.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP7789482 Magnesium bromide Magnesium bromide 7789-48-2 Price
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