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Conversion of Methanol to 2,2,3-trimethylbutane (Triptane) Over indium(III) Iodide

Conversion of Methanol to 2,2,3-trimethylbutane (Triptane) Over indium(III) Iodide

John E Bercaw, Paula L Diaconescu, Robert H Grubbs, Nilay Hazari, Richard D Kay, Jay A Labinger, Parisa Mehrkhodavandi, George E Morris, Glenn J Sunley, Patrick Vagner

Inorg Chem. 2007 Dec 24;46(26):11371-80.

PMID: 18047325

Abstract:

InI3 is able to catalyze the conversion of methanol to a mixture of hydrocarbons at 200 degrees C with one highly branched alkane, 2,2,3-trimethylbutane (triptane), being obtained in high selectivity. The mechanism for InI3-catalyzed reactions appears to be basically the same as that proposed for the previously studied ZnI2-catalyzed system in which sequential methylation of olefins is followed by competing reactions of the resulting carbocation: proton loss to give the next olefin vs hydride transfer to give the corresponding alkane. Although the reaction conditions and typical triptane yields achievable with ZnI2 and InI3 are quite similar, the two systems behave rather differently in a number of important particulars, including significant differences between the detailed product distributions. Most of the differences in behavior can be ascribed to the stronger Lewis acidity of InI3, including the ability to activate some alkanes, the higher activity for methylation of arenes, and the fact that methanol conversion can be observed at somewhat lower temperatures with InI3 than with ZnI2.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP13510355	Indium(III) iodide		13510-35-5	Price

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