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Cross-linked Helically Chiral poly-(γ-benzyl-L-glutamate) as Enantiodiscriminating Alignment Medium

Tobias Montag, Christina M Thiele

Chemistry. 2013 Feb 11;19(7):2271-4.

PMID: 23297249

Abstract:

The best of both worlds: By crosslinking poly-(γ-benzyl-L-glutamate) (PBLG), an alignment medium, which combines the scalability of cross-linked polymer gels (strain-induced-alignment media) with the enantiodiscriminating properties of helically chiral PBLG, was obtained. Spectra of excellent quality and residual dipolar couplings (RDCs) of the perfect size can be obtained for small organic compounds (see scheme; Bn = benzyl).

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP25014271 Poly-γ-benzyl-L-glutamate Poly-γ-benzyl-L-glutamate 25014-27-1 Price
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