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Crossbar Nanoarchitectonics of the Crosslinked Self-Assembled Monolayer

Crossbar Nanoarchitectonics of the Crosslinked Self-Assembled Monolayer

Hicham Hamoudi

Nanoscale Res Lett. 2014 Jun 9;9(1):287.

PMID: 24994952

Abstract:

A bottom-up approach was devised to build a crossbar device using the crosslinked SAM of the 5,5'-bis (mercaptomethyl)-2,2'-bipyridine-Ni(2+) (BPD- Ni(2+)) on a gold surface. To avoid metal diffusion through the organic film, the author used (i) nanoscale bottom electrodes to reduce the probability of defects on the bottom electrodes and (ii) molecular crosslinked technology to avoid metal diffusion through the SAMs. The properties of the crosslinked self-assembled monolayer were determined by XPS. I-V characteristics of the device show thermally activated hopping transport. The implementation of this type of architecture will open up new vistas for a new class of devices for transport, storage, and computing.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP894105987	5,5′-Bis(mercaptomethyl)-2,2′-bipyridine		894105-98-7	Price

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