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Crystal Structure of aqua-(2-{[2-({2-[bis-(carboxyl-ato-κ

Martin Wallin, Peter Turner, Andrew Katsifis, Mingshi Yang, Hak-Kim Chan

Acta Crystallogr E Crystallogr Commun. 2018 Jul 6;74(Pt 8):1054-1057.

PMID: 30116560

Abstract:

In the title GaIII complex compound with pentetic acid, [Ga(C14H20N3O10)(H2O)]·3H2O, the GaIII centre is bound in a slightly distorted octa-hedral coordination sphere by two amine N atoms, three carboxyl-ate O atoms and one water O atom. The complex mol-ecule exists as a zwitterion. In the crystal, the complexes are linked to each other via O-H⋯O and C-H⋯O hydrogen bonds, forming layers parallel to (001). Three uncoordinating water mol-ecules link the complex layers via O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds, forming a three-dimensional network.

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