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Cyclometallated gold(III) Hydroxides as Versatile Synthons for Au-N, Au-C Complexes and Luminescent Compounds

Cyclometallated gold(III) Hydroxides as Versatile Synthons for Au-N, Au-C Complexes and Luminescent Compounds

Dragoş-Adrian Roşca, Dan A Smith, Manfred Bochmann

Chem Commun (Camb). 2012 Jul 25;48(58):7247-9.

PMID: 22695754

Abstract:

The gold(III) hydroxide κ(3)-(C^N^C)*Au(OH) reacts with C-H and N-H compounds and arylboronic acids to produce a range of perfluoroaryls, N-heterocyclic and alkynyl compounds in high yields; some of which show unexpectedly strong modulation of their photoluminescence from yellow to blue [(C^N^C)* = 2,6-(C(6)H(3)Bu(t))(2)pyridine].

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP1303522	Gold(III) hydroxide		1303-52-2	Price

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