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Derivatives of Cyanonaphthyl-Substituted Phenanthroimidazole as Blue Emitters for Nondoped Organic Light-Emitting Diodes

Derivatives of Cyanonaphthyl-Substituted Phenanthroimidazole as Blue Emitters for Nondoped Organic Light-Emitting Diodes

Jayaraman Jayabharathi, Pavadai Nethaji, Venugopal Thanikachalam, Ramaiyan Ramya

ACS Omega. 2019 Mar 1;4(3):4553-4570.

PMID: 31459647

Abstract:

New multifunctional blue-emissive materials with superior thermal properties, viz., 4,4'-bis(1-(4-naphthyl)-1H-phenanthro[9,10-d]imidazol-2-yl)binaphthyl (NPIBN), 4,4'-bis(1-(4-cyanonaphthyl)-1H-phenanthro[9,10-d]imidazol-2-yl)biphenyl (CNPIBP), and 4,4'-bis(1-(4-cyanonaphthyl)-1H-phenanthro[9,10-d]imidazol-2-yl)binaphthyl (CNPIBN) have been synthesized. The said molecules show high photoluminescence quantum yield (Φs/f: NPIBN-0.75/0.68, CNPIBP-0.85/0.76, and CNPIBN-0.90/0.88). The fabricated nondoped/doped device with CNPIBN/4,4'-bis(carbazol-9-yl)biphenyl: CNPIBN display maximum efficiencies (ηex 4.96/5.4%; ηc 7.46/7.56 cd A-1; ηp 6.85/6.91 lm W-1) at low turn-on voltage (3.5/3.8 V). Nondoped devices based on D-π-A architecture, 4-(2-(5-(9H-carbazol-9-yl)thiophen-2-yl)-1H-phenanthro[9,10-d]imidazol-1-yl)naphthalene-1-carbonitrile exhibit maximum efficiencies (ηex 2.32%; ηc 4.00 cd A-1; ηp 3.42 lm W-1) compared to 4-(2-(5-(4-(diphenylamino)phenyl)thiophen-2-yl)-1H-phenanthro[9,10-d]imidazol-1-yl)naphthalene-1-carbonitrile (ηex 2.01%; ηc 3.89 cd A-1; ηp 3.15 lm W-1).

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP321694206	Bis-1,4-(4-methoxybenzenesulfonamidyl)naphthalene		321694-20-6	Price

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